SOME ASPECTS OF THE ORGANIC CHEMISTRY OF SULPHUR
SOME ASPECTS OF THE ORGANIC CHEMISTRY OF SULPHUR
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Date
1976-03
Authors
AMUPITAN, JOSEPH OLORUNJU
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Abstract
n t h i s report, the Wmgerodt-Kindler reaction has
been reviewed, and a. variant of the reaction has "been
developed.
In t h i s , good yields of thioamides have been obtained
"by reaction of aldehydes or ketones with s a l t s of v o l a t i le
amines and anhydrous sodium acetate in dimethylformamide
at moderate temperatures, thus avoiding the conventional
use of pressure vessels and high temperatures.
The thioamides with alkyl halides give S-alkylquaternary
s a l t s , which have been reacted with various
nucleophilic reagents: hydrazine hydrate, sodium borohydride
and diazomethane: giving interesting products.
Description
A THESIS PRESENTED TO THE
AHMADU BELLO UNIVERSITY FOR
THE DEGREE OF MASTER OP SCIENCE
Keywords
ASPECTS, ORGANIC, CHEMISTRY, SULPHUR